Dimethyl N-cyanodithioiminocarbonate → HCID 53804635, compound

HRID 261837Notes

Reaction equation

HRID 261837 reaction equation
[C:1]([N:3]=[C:4](SC)SC)#[N:2].[NH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][OH:15]>N1C=CC=CC=1>[C:1]([NH:3][C:4]([NH:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][OH:15])=[N:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][OH:15])#[N:2]

Participants

4

Reactant 2

HCID 66289Dimethyl N-cyanodithioiminocarbonateHCID 756345-Aminopentan-1-ol

Product 1

HCID 53804635HCID 53804635, compound

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

Heating dimethyl N-cyanodithioimidocarbonate with an excess of 5-aminopentan-1-ol in pyridine gives N-cyano-N',N"-bis(5-hydroxypentyl)guanidine, which may be treated with p-toluenesulphonyl chloride in pyridine and the product heated with thiourea in acetone to give N-cyano-N', N"-bis(5-(S-isothioureido)pentyl)guanidine.

Sources & evidence

ORD record
ord-444b23a70a4e41ff9eb154efd917c164
Source dataset
uspto-grants-1979_05
Patent number
US04152453

Reaction notes

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