Sodium ethoxide → HCID 21321539, compound

HRID 261894Notes

Reaction equation

HRID 261894 reaction equation
[CH2:1]([S:13]([CH:15]([CH2:19][C:20]([OH:22])=[O:21])[C:16]([OH:18])=[O:17])=[O:14])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].C(C(CC(O)=O)C(O)=S)CCCCCCCCCCC.CC[O-].[Na+:46]>C(O)C>[CH2:1]([S:13]([CH:15]([CH2:19][C:20]([O-:22])=[O:21])[C:16]([O-:18])=[O:17])=[O:14])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[Na+:46].[Na+:46]

Participants

5

Reactant 3

HCID 2723922Sodium ethoxideHCID 21321540HCID 21321540, compoundHCID 178443141HCID 178443141, compound

Product 1

HCID 21321539HCID 21321539, compoundYield 97.2%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent2×

Procedure

Three grams of the sulfoxide of n-dodecylthiosuccinic acid prepared above is dissolved in ethanol and mixed with a solution of 1.4 g of sodium ethylate dissolved in 25 ml of ethanol. The precipitated product is then filtered and dried in vacuo to give 3.3 g of disodium n-dodecylsulfinylsuccinate.

Workup

  1. filtrationThe precipitated product is then filtered
  2. customdried in vacuo

Sources & evidence

ORD record
ord-c6b393ed683a4c88bb6eae2fdb0b30fe
Source dataset
uspto-grants-1979_05
Patent number
US04152515

Reaction notes

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