Hydrogen Bromide → 4-Benzylbenzyl bromide

HRID 262198Notes

Reaction equation

HRID 262198 reaction equation
C(C1C=CC(CO)=CC=1)C1C=CC=CC=1.Br.CO[C:19]1[CH:33]=[CH:32][C:22]([CH2:23][C:24]2[CH:31]=[CH:30][C:27]([CH2:28][Br:29])=[CH:26][CH:25]=2)=[CH:21][CH:20]=1>>[CH2:23]([C:24]1[CH:25]=[CH:26][C:27]([CH2:28][Br:29])=[CH:30][CH:31]=1)[C:22]1[CH:21]=[CH:20][CH:19]=[CH:33][CH:32]=1

Participants

4

Reactant 3

HCID 260Hydrogen BromideHCID 5976144-(Phenylmethyl)benzenemethanolHCID 124638481-(Bromomethyl)-4-[(4-methoxyphenyl)methyl]benzene

Product 1

HCID 100382674-Benzylbenzyl bromide

Procedure

4-Benzylbenzyl bromide was prepared from 20 g. of 4-benzylbenzyl alcohol [Maquin et al., Compt. rend. 234, 629-31, 1952] and hydrogen bromide according to the procedure of Example 1, part (e). An oil (25.7 g.) was obtained which was used directly in the next reaction.

Workup

  1. customAn oil (25.7 g.) was obtained which
  2. customwas used directly in the next reaction

Sources & evidence

ORD record
ord-3396f1a26b9e40c2afefe39eeb1a8108
Source dataset
uspto-grants-1979_05
Patent number
US04153719

Reaction notes

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