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Methylamine → HCID 21319343、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methylamine | HCID 6329 | — |
| 反応物 | 8,9-dihydro-3-nitro-5H-benzocyclohepten-5-one | HCID 20094732 | — |
| 溶媒 | Benzene | HCID 241 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | HCID 21319343 | HCID 21319343 | — |
反応手順
A solution of 101.5 g of extemporaneously prepared monomethylamine in 700 ml of benzene was added at 20° C. with stirring to a mixture of 101.6 g of the product of Step B in 1 liter of ethanol and the mixture was stirred for 2 1/2 hours at room temperature and was allowed to stand for 12 hours. The mixture was evaporated to dryness under reduced pressure to obtain 125 g of 3-nitro-7-methylamino-6,7,8,9-tetrahydro [5H] benzocycloheptene-5-one in the form of a brown oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04154852 |
| 出典データセット | uspto-grants-1979_05 |
| ORD ID | ord-f667e65404f64712858a672b6d42047c |
| 出典メモ | uspto-grants-1979_05 |