HCID 53897072, compound → 4-Hydroxy-1-iodo trans-1-octene

HRID 262858Notes

Reaction equation

HRID 262858 reaction equation
[I:1][CH:2]=[CH:3][CH2:4][CH:5]([O:10][Si](C)(C)C)[CH2:6][CH2:7][CH2:8][CH3:9]>C(O)(=O)C.O1CCCC1.O>[OH:10][CH:5]([CH2:6][CH2:7][CH2:8][CH3:9])[CH2:4]/[CH:3]=[CH:2]/[I:1]

Participants

5

Reactant 1

HCID 53897072HCID 53897072, compound

Product 1

HCID 128512784-Hydroxy-1-iodo trans-1-octene

Reagents, catalysts & solvents 3

HCID 176Acetic AcidSolventHCID 962WaterSolventHCID 8028TetrahydrofuranSolvent

Procedure

A 23 g portion of 1-iodo-4-trimethylsilyloxy-1-octene is dissolved in a mixture of 200 ml of glacial acetic acid, 100 ml of tetrahydrofuran, and 50 ml of water. Concentration provides the named product.

Workup

  1. concentrationConcentration
  2. customprovides the named product

Sources & evidence

ORD record
ord-dd628361457143d2a18f4ff993a9cdf4
Source dataset
uspto-grants-1979_05
Patent number
US04154959

Reaction notes

Loading…