HCID 53897072, compound → 4-Hydroxy-1-iodo trans-1-octene

HRID 262896Notes

Reaction equation

HRID 262896 reaction equation
[I:1][CH:2]=[CH:3][CH2:4][CH:5]([O:10][Si](C)(C)C)[CH2:6][CH2:7][CH2:8][CH3:9]>C(O)(=O)C.O1CCCC1.O>[OH:10][CH:5]([CH2:6][CH2:7][CH2:8][CH3:9])[CH2:4]/[CH:3]=[CH:2]/[I:1]

Participants

5

Reactant 1

HCID 53897072HCID 53897072, compound

Product 1

HCID 128512784-Hydroxy-1-iodo trans-1-octene

Reagents, catalysts & solvents 3

HCID 176Acetic AcidSolventHCID 962WaterSolventHCID 8028TetrahydrofuranSolvent

Procedure

A 23 g portion of 1-iodo-4-trimethylsilyloxy-1-octene is dissolved in a mixture of 200 ml of glacial acetic acid, 100 ml of tetrahydrofuran, and 50 ml of water. Concentration provides the named product.

Workup

  1. concentrationConcentration
  2. customprovides the named product

Sources & evidence

ORD record
ord-682c71606a7b462ea8d316e11ad1b26c
Source dataset
uspto-grants-1979_05
Patent number
US04154954

Reaction notes

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