Methyl chloroformate → HCID 21316288, compound

HRID 263278Notes

Reaction equation

HRID 263278 reaction equation
[N:1]12[CH2:26][CH2:25][NH:24][CH2:23][CH2:22][NH:21][CH2:20][CH2:19][N:10]([CH2:11][CH2:12][O:13][CH2:14][CH2:15][O:16][CH2:17][CH2:18]1)[CH2:9][CH2:8][O:7][CH2:6][CH2:5][O:4][CH2:3][CH2:2]2.[C:27](Cl)(=[O:30])[O:28][CH3:29]>>[C:27]([N:24]1[CH2:23][CH2:22][N:21]([C:27]([O:28][CH3:29])=[O:30])[CH2:20][CH2:19][N:10]2[CH2:11][CH2:12][O:13][CH2:14][CH2:15][O:16][CH2:17][CH2:18][N:1]([CH2:2][CH2:3][O:4][CH2:5][CH2:6][O:7][CH2:8][CH2:9]2)[CH2:26][CH2:25]1)([O:28][CH3:29])=[O:30]

Participants

3

Reactant 2

HCID 6586Methyl chloroformateHCID 138109594,7,13,16-Tetraoxa-1,10,21,24-tetraazabicyclo[8.8.8]hexacosane

Product 1

HCID 21316288HCID 21316288, compound

Procedure

In a manner similar to that described in Example 7, treat 4,7,13,16-tetraoxa-1,10,21,24-tetraazabicyclo[8,8,8]-hexacosane (compound of Example 68B) with methyl chlorocarbonate Isolate and purify the resultant product in a manner similar to that described in Example 7 to obtain 21,24-dicarbomethoxy-4,7,13,16-tetraoxa-1,10,21,24-tetraazabicyclo[8,8,8]hexacosane, m.p. =86° C.

Workup

  1. customIsolate
  2. custompurify the resultant product in a manner similar to

Sources & evidence

ORD record
ord-94b34a6681d44a3e9e806366c72f8af7
Source dataset
uspto-grants-1979_05
Patent number
US04156683

Reaction notes

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