3-Methylthio-11-phenyl-11H-s-triazolo[3,4-b][3]benzazepine → HCID 21323326, compound

HRID 26502Notes

Reaction equation

HRID 26502 reaction equation
CS[C:3]1[N:12]2[C:6]([CH:7]([C:17]3[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=3)[C:8]3[CH:16]=[CH:15][CH:14]=[CH:13][C:9]=3[CH:10]=[CH:11]2)=[N:5][N:4]=1>[Ni]>[C:17]1([CH:7]2[C:8]3[CH:16]=[CH:15][CH:14]=[CH:13][C:9]=3[CH:10]=[CH:11][N:12]3[CH:3]=[N:4][N:5]=[C:6]23)[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=1

Participants

3

Reactant 1

HCID 213234263-Methylthio-11-phenyl-11H-s-triazolo[3,4-b][3]benzazepine

Product 1

HCID 21323326HCID 21323326, compound

Reagents, catalysts & solvents 1

HCID 935NickelCatalyst

Procedure

3-Methylthio-11-phenyl-11H-s-triazolo[3,4-b][3]benzazepine was treated with Raney nickel as described. This procedure provided 11-phenyl-11H-s-triazolo[3,4-b][3]benzazepine as crystals. Colorless prisms (as recrystallized from ethanol), m.p. 217°-218° C.

Sources & evidence

ORD record
ord-35982f5dd3544393a325bf07f225560f
Source dataset
uspto-grants-1979_04
Patent number
US04150139

Reaction notes

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