HuagongsheHuagongshe Chemistry Print Report · For research reference only
Selenium Dioxide → 8-methyl-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepin-11-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Selenium Dioxide | HCID 24007 | — |
| Reactant | 8-methyl-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine | HCID 21323337 | — |
| Product | 8-methyl-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepin-11-one | HCID 21323535 | — |
Reaction Steps
By a procedure similar to that described in Examples 13, the reaction of 8-methyl-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine with selenium dioxide gave 8-methyl-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepin-11-one as crystals. Recrystallization from methanol yielded colorless platelets melting at 178°-179° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04150139 |
| Source dataset | uspto-grants-1979_04 |
| ORD ID | ord-6f8d947953a24750bf9d8f76536b615e |
| Source note | uspto-grants-1979_04 |