m-Chloroperbenzoic acid → 9-methoxy-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine

HRID 26516Notes

Reaction equation

HRID 26516 reaction equation
[CH3:1][O:2][C:3]1[CH:18]=[CH:17][C:6]2[CH:7]=[CH:8][N:9]3[C:14]([S:15][CH3:16])=[N:13][N:12]=[C:10]3[CH2:11][C:5]=2[CH:4]=1.ClC1C=CC=C(C(OO)=[O:27])C=1>>[CH3:1][O:2][C:3]1[CH:18]=[CH:17][C:6]2[CH:7]=[CH:8][N:9]3[C:14]([S:15]([CH3:16])=[O:27])=[N:13][N:12]=[C:10]3[CH2:11][C:5]=2[CH:4]=1

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 213233549-methoxy-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine

Product 1

HCID 213234319-methoxy-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine

Procedure

By a procedure similar to that described in Example 17, 9-methoxy-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine was reacted with m-chloroperbenzoic acid to obtain 9-methoxy-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine. Colorless needles (as recrystallized from methanol), m.p. 176°-177° C.

Sources & evidence

ORD record
ord-b3f8702abf294495914bee6fab9635af
Source dataset
uspto-grants-1979_04
Patent number
US04150139

Reaction notes

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