m-Chloroperbenzoic acid → HCID 21323324, compound

HRID 26517Notes

Reaction equation

HRID 26517 reaction equation
[CH2:1]([S:3][C:4]1[N:13]2[C:7]([CH2:8][C:9]3[CH:17]=[CH:16][CH:15]=[CH:14][C:10]=3[CH:11]=[CH:12]2)=[N:6][N:5]=1)[CH3:2].ClC1C=CC=C(C(OO)=[O:26])C=1>>[CH2:1]([S:3]([C:4]1[N:13]2[C:7]([CH2:8][C:9]3[CH:17]=[CH:16][CH:15]=[CH:14][C:10]=3[CH:11]=[CH:12]2)=[N:6][N:5]=1)=[O:26])[CH3:2]

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 213234153-ethylthio-11H-s-triazolo[3,4-b][3]benzazepine

Product 1

HCID 21323324HCID 21323324, compound

Procedure

By a procedure similar to that described in Example 17, 3-ethylthio-11H-s-triazolo[3,4-b][3]benzazepine was reacted with m-chloroperbenzoic acid to obtain 3-ethylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine. Colorless needles (as recrystallized from ethyl acetate), m.p. 98°-99° C.

Sources & evidence

ORD record
ord-dbf6809aa78c41369a976b23dfb02a0f
Source dataset
uspto-grants-1979_04
Patent number
US04150139

Reaction notes

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