HRID265417

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID11430

Potassium Carbonate

CK2O3

HCID14798

Sodium Hydroxide

HNaO

HCID560317

Ethyl 9-bromononanoate

C11H21BrO2

结构：O=c1[nH]c(-c2ccccc2)c(-c2ccccc2)n1-c1ccccc1

HCID628544

1,4,5-Triphenyl-1,3-dihydro-2H-imidazol-2-one

C21H16N2O

PRODUCTS

生成物

结构：O=C(O)CCCCCCCCn1c(-c2ccccc2)c(-c2ccccc2)n(-c2ccccc2)c1=O

HCID22916411

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID702

Ethanol

C2H6O

溶剂HCID962

Water

H2O

溶剂HCID6569

Methyl ethyl ketone

C4H8O

PROCEDURE

实验过程

1,4,5-Triphenylimidazol-2-one was treated with ethyl 9-bromononanoate and potassium carbonate in butanone, followed by sodium hydroxide in ethanol and water, to give after work-up the title compound, m.p. 123°-124° C., Found:C, 76.9;H, 6.9;N, 5.7%;C30H32N2O3 requires: C, 76.9; H, 6.9; N, 6.0%

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-875414e9de0d4c98b502bba67e1cb404
来源数据集: uspto-grants-1997_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05648373
来源说明: uspto-grants-1997_07

反应 SMILES

[C:1]1([N:7]2[C:11]([C:12]3[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=3)=[C:10]([C:18]3[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=3)[NH:9][C:8]2=[O:24])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.Br[CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][C:34]([O:36]CC)=[O:35].C(=O)([O-])[O-].[K+].[K+].[OH-].[Na+]>CC(=O)CC.C(O)C.O>[C:1]1([N:7]2[C:11]([C:12]3[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=3)=[C:10]([C:18]3[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=3)[N:9]([CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][C:34]([OH:36])=[O:35])[C:8]2=[O:24])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1