indium(III)chloride → Diphenylphosphine

HRID 265818Notes

Reaction equation

HRID 265818 reaction equation
[C:1]1([PH:7](=O)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cl-].[In+3].[Cl-].[Cl-]>>[C:8]1([PH:7][C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1

Participants

3

Reactant 2

HCID 159675indium(III)chlorideHCID 254003Diphenylphosphine oxide

Product 1

HCID 70017DiphenylphosphineYield 88%

Conditions

Temperature
152 °C

Procedure

172 g (0.852 mol) of diphenylphosphine oxide and 0.8 g of indium chloride are mixed and heated to 152° C., the pressure being reduced simultaneously (8 mbar). Diphenylphosphine distills off through a descending condenser at a transition temperature of 132° C. After a total of 2 hours, the internal temperature has been raised to 195° C. 70 g of diphenylphosphine are obtained. That corresponds to a yield of 88% of theory.

Workup

  1. distillationDiphenylphosphine distills off through a descending condenser at a transition temperature of 132° C
  2. temperatureAfter a total of 2 hours, the internal temperature has been raised to 195° C

Sources & evidence

ORD record
ord-c27bd6846e4c4c0eafc550a6b816b19c
Source dataset
uspto-grants-1997_07
Patent number
US05648549

Reaction notes

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