HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → HCID 86747131, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | HCID 70051983 | HCID 70051983 | — |
| Reactant | HCID 178527989 | HCID 178527989 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 86747131 | HCID 86747131 | 60% |
Reaction Steps
A solution of 2-(5-phenyl-1-tetrazolyl)thiomethyl-4-ethylsaccharin (Example 30AE, 0.020 g) and 1-phenyltetrazol-5-thiol sodium salt (0.0026 g) in dimethylformamide (1 mL) was heated at 100° C. for three days, then poured into water. Recrystallization of the resulting solid from ethanol-water afforded 2-(4-phenyl-5-thioxo-1-tetrazolyl)methyl-4-ethylsaccharin, 0.012 g, 60% yield, mp 127°-129° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05650422 |
| Source dataset | uspto-grants-1997_07 |
| ORD ID | ord-682a082d5d3545fb84747d7ab80803b1 |
| Source note | uspto-grants-1997_07 |