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HRID266471

反应详情

EQUATION

反应方程式

HRID 266471 的结构方程式

REACTANTS

反应物

3
结构：CCO.O
HCID19096565

未命名化合物

结构：COc1cc2c(c(C(C)C)c1OC)C(=O)N(CCl)S2(=O)=O
HCID70044954

未命名化合物

结构：Sc1nnnn1-c1ccccc1.[Na]
HCID178527989

未命名化合物

PRODUCTS

生成物

1
结构：COc1cc2c(c(C(C)C)c1OC)C(=O)N(CSc1nnnn1-c1ccccc1)S2(=O)=O
HCID44341378

未命名化合物

收率 51%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

By the method of Example 44 condensation of 2-chloromethyl-4-isopropyl-5,6-dimethoxysaccharin (1.46 g) and 1-phenyltetrazol-5-thiol sodium salt (0.92 g) in dimethylformamide (5 mL) and recrystallization of the product from ethanol-water afforded 2-(1-phenyltetrazol-5-yl)thiomethyl-4-isopropyl-5,6-dimethoxy-saccharin, 1.05 g, 51% yield, mp 69°-71° C.