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HRID266480

反应详情

EQUATION

反应方程式

HRID 266480 的结构方程式

REACTANTS

反应物

2
结构：O=S(=O)(Cl)Cl
HCID24648

Sulfuryl chloride

Cl2O2S

结构：CCc1c(OC)c(C)c(OC)c2c1C(=O)N(CSc1ccccc1)S2(=O)=O
HCID70050753

未命名化合物

PRODUCTS

生成物

1
结构：CCc1c(OC)c(C)c(OC)c2c1C(=O)N(CCl)S2(=O)=O
HCID70052343

未命名化合物

收率 22%

PROCEDURE

实验过程

By the method of Example 21 phenylthiomethylation of 4-ethyl-5,7-dimethoxy-6-methylsaccharin (0.65 g) with chloromethyl phenyl sulfide (0.24 mL) gave 2-phenylthiomethyl-4-ethyl-5,7-dimethoxy-6-methylsaccharin, reaction of which with sulfuryl chloride gave 2-chloromethyl-4-ethyl-5,7-dimethoxy-6-methylsaccharin, 0.16 g, 22% yield.