Cyanuric chloride → HCID 136426879, compound

HRID 267180Notes

Reaction equation

HRID 267180 reaction equation
[N:1]1[C:8]([Cl:9])=[N:7][C:5]([Cl:6])=[N:4][C:2]=1Cl.[C:10]([C:14]1[CH:20]=[CH:19][CH:18]=[C:17]([C:21]([CH3:24])([CH3:23])[CH3:22])[C:15]=1[O-:16])([CH3:13])([CH3:12])[CH3:11].[Na+]>O1CCOCC1>[C:21]([C:17]1[CH:18]=[C:19]([C:2]2[N:4]=[C:5]([Cl:6])[N:7]=[C:8]([Cl:9])[N:1]=2)[CH:20]=[C:14]([C:10]([CH3:13])([CH3:12])[CH3:11])[C:15]=1[OH:16])([CH3:24])([CH3:23])[CH3:22]

Participants

4

Reactant 2

HCID 7954Cyanuric chlorideHCID 23662146HCID 23662146, compound

Product 1

HCID 136426879HCID 136426879, compound

Reagents, catalysts & solvents 1

HCID 312751,4-DioxaneSolvent

Procedure

To 18.35 g of cyanuric chloride dissolved in dioxane at 5°C was added 22.83 g of sodium 2,6-di-t-butylphenoxide over a period of 10 to 15 minutes. The reaction was maintained below 10°C for 1 hour after which it was warmed to room temperature and filtered to remove precipitated salt. The filtrate was concentrated to dryness under reduced pressure. The product was recrystallized from petroleum ether and had a melting point of 178°-179°C.

Workup

  1. temperatureThe reaction was maintained below 10°C for 1 hour after which it
  2. filtrationfiltered
  3. customto remove
  4. customprecipitated salt
  5. concentrationThe filtrate was concentrated to dryness under reduced pressure
  6. customThe product was recrystallized from petroleum ether

Sources & evidence

ORD record
ord-bdb48433008d4bd68087704fba69130f
Source dataset
uspto-grants-1976_03
Patent number
US03941745

Reaction notes

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