Hydrochloric Acid → HCID 21556718, compound

HRID 267265Notes

Reaction equation

HRID 267265 reaction equation
[CH2:1]([OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[CH3:20][O:21][C:22]([CH2:24][C:25]#[N:26])=[O:23].[ClH:27]>C(OCC)C>[ClH:27].[CH3:20][O:21][C:22]([CH2:24][C:25](=[NH:26])[O:19][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])=[O:23]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 7747Methyl cyanoacetateHCID 8221Stearyl Alcohol

Product 1

HCID 21556718HCID 21556718, compoundYield 46.8%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

In a mixture of 27.0 parts of stearyl alcohol in 200 volume parts of dry ethyl ether and 9.9 parts of methyl cyano acetate was introduced about 5.3 parts of dry hydrogen chloride gas at room temperature, followed by keeping at room temperature for 2 days. The resulting white precipitates were washed with ethylether and dried to give 19.0 parts of stearyl methoxycarbonylacetimidate hydrochloride melting at 83° to 85°C (decomposition). Yield: 46.8%

Workup

  1. customThe resulting white precipitates
  2. washwere washed with ethylether
  3. customdried

Sources & evidence

ORD record
ord-aa2f25c9885f4ab990d69abcfb05d88f
Source dataset
uspto-grants-1976_03
Patent number
US03941823

Reaction notes

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