Diethylamine → HCID 131710079, compound

HRID 267386Notes

Reaction equation

HRID 267386 reaction equation
[CH2:1]([NH:3][CH2:4][CH3:5])[CH3:2].[Cl:6][CH:7]([C:11]1[CH:16]=[CH:15][C:14]([C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=2[Cl:23])=[CH:13][CH:12]=1)[C:8]([OH:10])=[O:9]>CCCCCC>[CH2:1]([NH2+:3][CH2:4][CH3:5])[CH3:2].[Cl:6][CH:7]([C:11]1[CH:16]=[CH:15][C:14]([C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=2[Cl:23])=[CH:13][CH:12]=1)[C:8]([O-:10])=[O:9]

Participants

4

Reactant 2

HCID 8021DiethylamineHCID 21523009HCID 21523009, compound

Product 1

HCID 131710079HCID 131710079, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

Anhydrous diethylamine (0.11 moles) is added dropwise to a stirred solution of α, 2'-dichloro-4-biphenylylacetic acid (0.10 moles) in 100 ml. of n-hexane at 0°C. The precipitate is collected on a filter, washed with n-hexane, and dried in a vacuum desiccator to obtain α, 2'-dichloro-4-biphenylylacetic acid, diethylammonium salt.

Workup

  1. customat 0°C
  2. customThe precipitate is collected on a filter
  3. washwashed with n-hexane
  4. customdried in a vacuum desiccator

Sources & evidence

ORD record
ord-b9bb7ef2671042c9b1b1eddf0f54e220
Source dataset
uspto-grants-1976_03
Patent number
US03941821

Reaction notes

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