Toluene → HCID 23339073, compound

HRID 26746Notes

Reaction equation

HRID 26746 reaction equation
[CH3:1][CH:2]([N:4]1[CH2:9][CH2:8][C:7](=O)[CH2:6][CH2:5]1)[CH3:3].CC1C=CC(S(O)(=O)=O)=CC=1.CC1C=CC=CC=1.[C:29]1([NH2:35])[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1>O>[CH3:1][CH:2]([N:4]1[CH2:9][CH2:8][C:7](=[N:35][C:29]2[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=2)[CH2:6][CH2:5]1)[CH3:3]

Participants

6

Reactant 4

HCID 1140Toluene2×HCID 6101p-Toluenesulfonic acidHCID 6115AnilineHCID 793131-(Isopropyl)-4-piperidone

Product 1

HCID 23339073HCID 23339073, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

To a stirred and refluxing mixture of 48 parts of 1-(1-methylethyl)-4-piperidinone, 1 part of 4-methylbenzenesulfonic acid and 540 parts of methylbenzene is added dropwise a solution of 30 parts of benzenamine in 90 parts of methylbenzene. Upon completion, the whole is stirred and refluxed for 3 hours with water-separator. The reaction mixture is evaporated, yielding 72 parts of N-[1-(1-methylethyl)-4-piperidinylidene]benzenamine as a residue.

Workup

  1. temperaturerefluxing
  2. stirringUpon completion, the whole is stirred
  3. customThe reaction mixture is evaporated

Sources & evidence

ORD record
ord-f0b6dba5669d4ed3986a0829758fae81
Source dataset
uspto-grants-1979_04
Patent number
US04151286

Reaction notes

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