Hydrogen Peroxide → HCID 21555235, compound

HRID 267599Notes

Reaction equation

HRID 267599 reaction equation
[CH:1]1([CH2:7][S:8][C:9]2[C:10](=[O:18])[CH2:11][C:12]([CH3:17])([CH3:16])[CH2:13][C:14]=2[OH:15])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[OH:19]O>C(O)(=O)C>[CH:1]1([CH2:7][S:8]([C:9]2[C:14](=[O:15])[CH2:13][C:12]([CH3:16])([CH3:17])[CH2:11][C:10]=2[OH:18])=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]1

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 21555244HCID 21555244, compound

Product 1

HCID 21555235HCID 21555235, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

A mixture of 2-(cyclohexylmethylthio)-3-hydroxy-5,5-dimethyl-2-cyclohexen-1-one (8.0 g., 0.029 mole), 50 ml. of glacial acetic acid and 30 percent hydrogen peroxide (3.26 g., 0.029 mole) was allowed to stand at room temperature for 24 hours. The solution was then poured into ice-water, and the precipitated pink crystals were filtered and dried (7.7 g., m.p. 77°-79.5°C.).

Workup

  1. filtrationthe precipitated pink crystals were filtered
  2. customdried (7.7 g., m.p. 77°-79.5°C.)

Sources & evidence

ORD record
ord-5a131ce2acc74d4792765ea0f821ff67
Source dataset
uspto-grants-1976_03
Patent number
US03943176

Reaction notes

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