Acetic Acid → HCID 21555256, compound

HRID 267600Notes

Reaction equation

HRID 267600 reaction equation
[OH:1][C:2]1[CH2:7][C:6]([CH3:9])([CH3:8])[CH2:5][C:4](=[O:10])[C:3]=1[S:11][CH2:12][CH:13]([CH3:15])[CH3:14].OO.C(O)(=[O:20])C>CCCCCC>[OH:10][C:4]1[CH2:5][C:6]([CH3:8])([CH3:9])[CH2:7][C:2](=[O:1])[C:3]=1[S:11]([CH2:12][CH:13]([CH3:15])[CH3:14])=[O:20]

Participants

5

Reactant 3

HCID 176Acetic AcidHCID 784Hydrogen PeroxideHCID 21555254HCID 21555254, compound

Product 1

HCID 21555256HCID 21555256, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

A mixture of 3-hydroxy-2-isobutylthio-5,5-dimethyl-2-cyclohexen-1-one (10 g., 0.044 mole), 30 percent hydrogen peroxide (5.0 g., 0.044 mole), and 100 ml. of glacial acetic acid was allowed to stand at room temperature for 19 hours. The solution was poured into ice-water and the solid filtered to give 4.7 g. of crude product. After two from hexane the pure product was obtained as pink crystals 3.3 g., m.p. b 48.5°-50°C.

Workup

  1. filtrationthe solid filtered
  2. customto give 4.7 g

Sources & evidence

ORD record
ord-fe936d9fd1194e9cb9e5326aa869491c
Source dataset
uspto-grants-1976_03
Patent number
US03943176

Reaction notes

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