Hydrogen Peroxide → HCID 21555251, compound

HRID 267601Notes

Reaction equation

HRID 267601 reaction equation
[OH:1][C:2]1[CH2:7][C:6]([CH3:9])([CH3:8])[CH2:5][C:4](=[O:10])[C:3]=1[S:11][CH2:12][CH2:13][CH:14]([CH3:16])[CH3:15].[OH:17]O>C(O)(=O)C>[OH:10][C:4]1[CH2:5][C:6]([CH3:8])([CH3:9])[CH2:7][C:2](=[O:1])[C:3]=1[S:11]([CH2:12][CH2:13][CH:14]([CH3:16])[CH3:15])=[O:17]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 21555236HCID 21555236, compound

Product 1

HCID 21555251HCID 21555251, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

A mixture of 3-hydroxy-2-isopentylthio-5,5-dimethyl-2-cyclohexen-1-one (10 g., 0.041 mole), 30 percent hydrogen peroxide (4.7 g., 0.041 mole), and 100 ml. of glacial acetic acid was allowed to stand at room temperature for 24 hours. The mixture was poured into ice water and the precipitated pink crystals were filtered and dried (9.1 g., m.p. 64.5°-66°C.).

Workup

  1. filtrationthe precipitated pink crystals were filtered
  2. customdried (9.1 g., m.p. 64.5°-66°C.)

Sources & evidence

ORD record
ord-0b6b35c775154489b36b7df1240ed732
Source dataset
uspto-grants-1976_03
Patent number
US03943176

Reaction notes

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