Hydrogen Peroxide → HCID 21555257, compound

HRID 267602Notes

Reaction equation

HRID 267602 reaction equation
[Cl:1][C:2]1[CH:19]=[CH:18][C:5]([CH2:6][S:7][C:8]2[C:9](=[O:17])[CH2:10][C:11]([CH3:16])([CH3:15])[CH2:12][C:13]=2[OH:14])=[CH:4][CH:3]=1.[OH:20]O>C(O)(=O)C>[Cl:1][C:2]1[CH:3]=[CH:4][C:5]([CH2:6][S:7]([C:8]2[C:13](=[O:14])[CH2:12][C:11]([CH3:16])([CH3:15])[CH2:10][C:9]=2[OH:17])=[O:20])=[CH:18][CH:19]=1

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 21555229HCID 21555229, compound

Product 1

HCID 21555257HCID 21555257, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

A mixture of 2-(p-chlorobenzylthio)-3-hydroxy-5,5-dimethyl-2-cyclohexen-1-one (10.0 g., 0.0338 mole), 30 percent hydrogen peroxide (3.83 g., 0.0338 mole), and 350 ml. of glacial acetic acid was allowed to stand at room temperature for 23 hours. The solution was poured into ice water, and the precipitated pink solid was filtered and dried (10 g., m.p. 143.5°-145°C.).

Workup

  1. filtrationthe precipitated pink solid was filtered
  2. customdried (10 g., m.p. 143.5°-145°C.)

Sources & evidence

ORD record
ord-9ca7f08d8f8f4f09b1ccd90ffb5581ab
Source dataset
uspto-grants-1976_03
Patent number
US03943176

Reaction notes

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