Hydrogen Peroxide → HCID 21555245, compound

HRID 267603Notes

Reaction equation

HRID 267603 reaction equation
[F:1][C:2]1[CH:19]=[CH:18][C:5]([CH2:6][S:7][C:8]2[C:9](=[O:17])[CH2:10][C:11]([CH3:16])([CH3:15])[CH2:12][C:13]=2[OH:14])=[CH:4][CH:3]=1.[OH:20]O>C(O)(=O)C>[F:1][C:2]1[CH:3]=[CH:4][C:5]([CH2:6][S:7]([C:8]2[C:13](=[O:14])[CH2:12][C:11]([CH3:16])([CH3:15])[CH2:10][C:9]=2[OH:17])=[O:20])=[CH:18][CH:19]=1

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 21555232HCID 21555232, compound

Product 1

HCID 21555245HCID 21555245, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

A mixture of 2-(p-fluorobenzylthio)-3-hydroxy-5,5-dimethyl-2-cyclohexen-1-one (12.4 g., 0.0443 mole) 30 percent hydrogen peroxide (5.0 g., 0.044 mole) and 100 ml. of glacial acetic acid was allowed to stand at room temperature for 24 hours. The solution was poured into ice water and the precipitated pink crystals were filtered and dried (12.3 g., m.p. 122°-125°C.).

Workup

  1. filtrationthe precipitated pink crystals were filtered
  2. customdried (12.3 g., m.p. 122°-125°C.)

Sources & evidence

ORD record
ord-c33b709b07af4cb981bed64545c39f70
Source dataset
uspto-grants-1976_03
Patent number
US03943176

Reaction notes

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