Hydrogen Peroxide → HCID 21555252, compound

HRID 267604Notes

Reaction equation

HRID 267604 reaction equation
[OH:1][C:2]1[CH2:7][C:6]([CH3:9])([CH3:8])[CH2:5][C:4](=[O:10])[C:3]=1[S:11][CH2:12][C:13]1[CH:18]=[CH:17][C:16]([CH3:19])=[CH:15][CH:14]=1.[OH:20]O>C(O)(=O)C>[OH:10][C:4]1[CH2:5][C:6]([CH3:8])([CH3:9])[CH2:7][C:2](=[O:1])[C:3]=1[S:11]([CH2:12][C:13]1[CH:18]=[CH:17][C:16]([CH3:19])=[CH:15][CH:14]=1)=[O:20]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 21555249HCID 21555249, compound

Product 1

HCID 21555252HCID 21555252, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

A mixture of 3-hydroxy-5,5-dimethyl-2-(p-methylbenzylthio)-2-cyclohexen-1-one (10 g., 0.036 mole), 30 percent hydrogen peroxide (4.11 g., 0.0362 mole), and 100 ml. of glacial acetic acid was allowed to stand at room temperature for 24 hours. The solution was poured into ice water, and the resulting pink solid was filtered and dried to give pure product (9.9 g., m.p. 89°-90.5°C.).

Workup

  1. filtrationthe resulting pink solid was filtered
  2. customdried
  3. customto give pure product (9.9 g., m.p. 89°-90.5°C.)

Sources & evidence

ORD record
ord-05d525baf16a406fa2d6961b59b6bf83
Source dataset
uspto-grants-1976_03
Patent number
US03943176

Reaction notes

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