4-Cyanophenol → p-[(1,5-Dimethyl-hexyl)-oxy]-benzonitrile

HRID 267711Notes

Reaction equation

HRID 267711 reaction equation
Br[CH:2]([CH2:4][CH2:5][CH2:6][CH:7]([CH3:9])[CH3:8])[CH3:3].[OH:10][C:11]1[CH:18]=[CH:17][C:14]([C:15]#[N:16])=[CH:13][CH:12]=1>>[CH3:3][CH:2]([O:10][C:11]1[CH:18]=[CH:17][C:14]([C:15]#[N:16])=[CH:13][CH:12]=1)[CH2:4][CH2:5][CH2:6][CH:7]([CH3:9])[CH3:8]

Participants

3

Reactant 2

HCID 130194-CyanophenolHCID 1383322-Bromo-6-methylheptane

Product 1

HCID 21487583p-[(1,5-Dimethyl-hexyl)-oxy]-benzonitrile

Procedure

2-bromo-6-methyl-heptane was reacted with 3-methoxy-4-hydroxy-5-bromo-benzaldehyde to obtain 5-bromo-4-[(1,5-dimethyl-hexyl)-oxy]-m-anisaldehyde (boiling point = 190°-193°C/0.1 mmHg); 2-bromo-6-methyl-heptane was reacted with p-hydroxy-benzonitrile to obtain p-[(1,5-dimethyl-hexyl)-oxy]-benzonitrile (boiling point = 165°-168°C/1.0 mmHg);

Sources & evidence

ORD record
ord-7d23c002014e4648ac90ac45739e2d1e
Source dataset
uspto-grants-1976_03
Patent number
US03944531

Reaction notes

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