Methylamine → (Cyclohexylmethyl)(methyl)amine

HRID 268284Notes

Reaction equation

[CH2:1]([N:8]1CCCC[CH2:9]1)[CH:2]1[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1.CN.C1CCCCC=1.CN(CC1CCCCC1)CC1CCCCC1>>[CH:2]1([CH2:1][NH:8][CH3:9])[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1

Participants

Reactant 4

HCID 6329Methylamine

HCID 8079Cyclohexene

HCID 71660Leptacline

HCID 21551827Di(cyclohexylmethyl)methylamine

Product 1

HCID 117276(Cyclohexylmethyl)(methyl)amine

Procedure

In place of piperidine of Example 4, there was used methylamine as the amine reactant. Ca. 70% of cyclohexene was converted to methyl-di-(cyclohexylmethyl)-amine. N-formyl derivative of N-(cyclohexylmethyl)-methylamine was also isolated as a further product.

Sources & evidence

ORD record: ord-0cb9668da1b04bf2b2f2e0f98094f88f
Source dataset: uspto-grants-1976_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03947458

Reaction notes

Loading…