tert-Butylhydrazine → 3-tert-Butyl-3,4,9-triaza-tricyclo[5.3.1.0 2,6]undeca-2(6),4-diene
Reaction equation
C([N:8]1[CH2:14][CH:13]2[CH2:15][CH:10]([C:11](=[CH:17][N:18](C)C)[C:12]2=O)[CH2:9]1)C1C=CC=CC=1.[C:21]([NH:25]N)([CH3:24])([CH3:23])[CH3:22]>>[C:21]([N:25]1[N:18]=[CH:17][C:11]2[CH:10]3[CH2:15][CH:13]([CH2:14][NH:8][CH2:9]3)[C:12]1=2)([CH3:24])([CH3:23])[CH3:22]Participants
3
Procedure
Following the method described in Example 14, 3-benzyl-7-dimethylaminomethylene-3-aza-bicyclo[3.2.1]octan-6-one and t-butyl hydrazine were converted to the title compound in 7.5% overall yield. APCl MS m/z 206.2 (M+H)+.
Sources & evidence
- ORD record
- ord-936d041243f34af0b3f9023806853fbf
- Source dataset
- uspto-grants-2008_11
- Patent number
- US07456177B2
Reaction notes
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