1,1-Bis(methylthio)-2-nitroethylene → HCID 178457407, compound

HRID 27391Notes

Reaction equation

HRID 27391 reaction equation
[CH3:1][C:2]1[N:3]=[CH:4][NH:5][C:6]=1[CH2:7][S:8][CH2:9][CH2:10]CN.CSC(SC)=[CH:16][N+:17]([O-])=O.[N+:22]([CH:25]=[C:26](SC)[NH:27][CH2:28][CH2:29][CH2:30]SCC1NC=NC=1C)([O-:24])=[O:23].C(N)C#C>>[N+:22]([CH:25]=[C:26]([NH:27][CH2:28][C:29]#[CH:30])[NH:17][CH2:16][CH:9]([S:8][CH2:7][C:6]1[NH:5][CH:4]=[N:3][C:2]=1[CH3:1])[CH3:10])([O-:24])=[O:23]

Participants

5

Reactant 4

HCID 836231,1-Bis(methylthio)-2-nitroethyleneHCID 239041PropargylamineHCID 178433286HCID 178433286, compoundHCID 178503823HCID 178503823, compound

Product 1

HCID 178457407HCID 178457407, compound

Procedure

When 3-[(4-methyl-1H-imidazol-5-yl)methylthio]propylamine [prepared according to the procedure described in Belgian Pat. No. 804,144] is reacted with 1,1-bis(methylthio)-2-nitroethylene according to the procedure of Example 6, Step A, and the resultant 1-nitro-2-methylthio-2-{3-[(4-methyl-1H-imidazol-5-yl)methylthio]propylamino}ethylene is treated with propargylamine by the procedure of Example 6, Step B, the title compound is produced.

Sources & evidence

ORD record
ord-e58d0ecb93784ed5b17d4c3295ffa565
Source dataset
uspto-grants-1980_09
Patent number
US04221737

Reaction notes

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