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HRID274563

反应详情

EQUATION

反应方程式

HRID 274563 的结构方程式

REACTANTS

反应物

1
结构：COc1cc(C(O)c2cccs2)cc([N+](=O)[O-])c1OC
HCID21458951

未命名化合物

PRODUCTS

生成物

1
结构：COc1cc(C(=O)c2cccs2)cc([N+](=O)[O-])c1OC
HCID17977694

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Mn+4].[O-2].[O-2]
催化剂HCID178418406

未命名化合物

结构：CC(C)=O
溶剂HCID180

Acetone

C3H6O

PROCEDURE

实验过程

9.9 g of α-(3,4-dimethoxy-5-nitrophenyl)-2-thiophenemethanol dissolved in 300 ml of acetone are treated with 90 g of manganese dioxide and heated under reflux for 4 hours. The manganese dioxide is removed by suction filtration and the filtrate is evaporated. There is obtained 3,4-dimethoxy-5-nitrophenyl 2-thienyl ketone of m.p. 102°-104° (from methylene chloride/hexane).

WORKUP

后处理

  1. temperatureheated
  2. temperatureunder reflux for 4 hours
  3. customThe manganese dioxide is removed by suction filtration
  4. customthe filtrate is evaporated