Methyl 3-chloro-4-hydroxyphenylacetate → HCID 12347957, compound

HRID 27601Notes

Reaction equation

HRID 27601 reaction equation
[CH2:1]([O:4][C:5]1[CH:12]=[CH:11][C:8]([CH2:9]Cl)=[CH:7][CH:6]=1)[CH:2]=[CH2:3].C[O:14][C:15](=[O:25])[CH2:16][C:17]1[CH:22]=[CH:21][C:20]([OH:23])=[C:19]([Cl:24])[CH:18]=1>C(OCC)(=O)C>[Cl:24][C:19]1[CH:18]=[C:17]([CH2:16][C:15]([OH:14])=[O:25])[CH:22]=[CH:21][C:20]=1[O:23][CH2:9][C:8]1[CH:11]=[CH:12][C:5]([O:4][CH2:1][CH:2]=[CH2:3])=[CH:6][CH:7]=1

Participants

4

Reactant 2

HCID 92625Methyl 3-chloro-4-hydroxyphenylacetateHCID 123479361-Allyloxy-4-chloromethyl-benzene

Product 1

HCID 12347957HCID 12347957, compoundYield 49.6%

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

The noted compound was prepared in accordance with the procedure described in section (f) from 4-allyloxybenzyl chloride and methyl-3-chloro-4-hydroxy-phenylacetate in 49.6% yield, m.p. 106°-107° C. (ethyl acetate).

Workup

  1. customThe noted compound was prepared in accordance with the procedure

Sources & evidence

ORD record
ord-a619876782ee4256b220861a32736ee3
Source dataset
uspto-grants-1980_09
Patent number
US04221919

Reaction notes

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