Hydroxyamine hydrochloride → HCID 22623976, compound

HRID 279013Notes

Reaction equation

HRID 279013 reaction equation
[CH:1]1[C:16]2[C:17]3[C:4]([C:5](=O)[O:6][C:7](=[O:18])[C:8]=3[CH:9]=[C:10]3[C:15]=2[CH2:14][O:13][CH2:12][O:11]3)=[CH:3][CH:2]=1.Cl.[NH2:21][OH:22]>N1C=CC=CC=1>[OH:22][N:21]1[C:5](=[O:6])[C:4]2=[CH:3][CH:2]=[CH:1][C:16]3[C:17]2=[C:8]([CH:9]=[C:10]2[C:15]=3[CH2:14][O:13][CH2:12][O:11]2)[C:7]1=[O:18]

Participants

4

Reactant 2

HCID 443297Hydroxyamine hydrochlorideHCID 22623921HCID 22623921, compound

Product 1

HCID 22623976HCID 22623976, compoundYield 110.6%

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

11H-5,8,10-Trioxabenzo[de]anthracene-4,6-dione (0.14 g, 0.5 mmol, from Example K1) and hydroxylamine hydrochloride (0.06 g, 0.9 mmol) were reacted in pyridine (4.0 mL) following the procedure of Example 1 to give 0.15 g of the title compound, mp >350° C.;

Sources & evidence

ORD record
ord-84e6cf82f4714832830e7d18aad1c6e9
Source dataset
uspto-grants-2002_03
Patent number
US06362181B1

Reaction notes

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