Hydrochloric Acid → HCID 22111203, compound

HRID 27908Notes

Reaction equation

HRID 27908 reaction equation
[C:1]([NH:4][CH:5]1[CH2:17][C:16]2[C:15]3[C:10](=[CH:11][C:12]([O:18]CC4C=CC=CC=4)=[CH:13][CH:14]=3)[NH:9][C:8]=2[CH2:7][CH2:6]1)(=[O:3])[CH3:2].Cl>[Pd].C(O)C>[C:1]([NH:4][CH:5]1[CH2:17][C:16]2[C:15]3[C:10](=[CH:11][C:12]([OH:18])=[CH:13][CH:14]=3)[NH:9][C:8]=2[CH2:7][CH2:6]1)(=[O:3])[CH3:2]

Participants

5

Reactant 2

HCID 313Hydrochloric AcidHCID 233404763-Acetamido-7-(benzyloxy)-1,2,3,4-tetrahydrocarbazole

Product 1

HCID 22111203HCID 22111203, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

3-Acetamido-7-(benzyloxy)-1,2,3,4-tetrahydrocarbazole (16 g.) was hydrogenated in 200 ml. of ethyl alcohol containing 6 ml. of concentrated hydrochloric acid and 3 g. of 10% palladium on charcoal at 40 psig following a procedure similar to that described in Example 2B to yield 3-acetamido-7-hydroxy-1,2,3,4-tetrahydrocarbazole as a foam.

Sources & evidence

ORD record
ord-8989c8b9c44447e3b3e9a7959ae28084
Source dataset
uspto-grants-1980_09
Patent number
US04224335

Reaction notes

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