Benzaldehyde → N-(2-Chlorophenyl)(phenyl)methanimine N-oxide

HRID 27916Notes

Reaction equation

HRID 27916 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[NH:8][OH:9].[CH:10](=O)[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>C(O)C>[C:11]1([CH:10]=[N+:8]([C:3]2[CH:4]=[CH:5][CH:6]=[CH:7][C:2]=2[Cl:1])[O-:9])[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1

Participants

4

Reactant 2

HCID 240BenzaldehydeHCID 1515172-Chlorophenylhydroxylamine

Product 1

HCID 71404765N-(2-Chlorophenyl)(phenyl)methanimine N-oxide

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent2×

Procedure

o-Chlorophenylhydroxylamine (0.05 moles) was dissolved in warm 95% ethanol (20 cc) and was treated with benzaldehyde (0.05 moles) with vigorous stirring. The solid which formed was from ethanol to give α-phenyl-N-2-chlorophenylnitrone.

Workup

  1. customThe solid which formed

Sources & evidence

ORD record
ord-848a4770c20e4cab8c81bd5cfa5b6156
Source dataset
uspto-grants-1980_09
Patent number
US04224340

Reaction notes

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