HRID279791

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID14798

Sodium Hydroxide

HNaO

反应SMILES：COC(=O)C(C)N1CCCCCC(N=[N+]=[N-])C1=O

HCID23322546

未命名化合物

PRODUCTS

产物

反应SMILES：CC(C(=O)O)N1CCCCCC(N=[N+]=[N-])C1=O

HCID23322533

未命名化合物

PROCEDURE

实验过程

Saponify this ester with dilute NaOH, acidify the reaction mixture and extract with methylene chloride. After drying and concentration of the extracts, isolate 3-azido-1-(1-carboxyethyl)-perhydroazocin-2-one. Fractionally crystallize this material from acetonitrile as the dicyclohexylamine salt to obtain the desired diastereomer.

WORKUP

后处理

extractionextract with methylene chloride
customAfter drying