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HRID280042

反应详情

EQUATION

反应方程式

HRID 280042 的结构方程式

REACTANTS

反应物

3
结构：CCO
HCID702

Ethanol

C2H6O

结构：CC(=O)OC(C)=O
HCID7918

Acetic anhydride

C4H6O3

结构：N[C@H](Cc1ccc([N+](=O)[O-])cc1)C(=O)O
HCID679497

4-Nitro-D-phenylalanine

C9H10N2O4

PRODUCTS

生成物

1
结构：CC(=O)N[C@H](Cc1ccc([N+](=O)[O-])cc1)C(=O)O
HCID7039504

N-Acetyl-4-nitro-D-phenylalanine

C11H12N2O5

AUXILIARIES

试剂、催化剂与溶剂

1
结构：[Na+].[OH-]
溶剂HCID14798

Sodium Hydroxide

HNaO

PROCEDURE

实验过程

Compound 6 (6.20 g) was acetylated with acetic anhydride (9 ml) in aqueous sodium hydroxide at pH 9 and 4° C. according to the procedure of Yoshida and Ishii [J. Biochem., 71, 185-191 (1972)]. Obtained 5.32 g (71.4%), mp 165°-166° C., [α]D25 =-46.2 °(c =2.8, ethanol)