HuagongsheHuagongshe Chemistry Print Report · For research reference only
p-nitrophenol sodium salt → 1-Methoxy-4-[(4-nitrophenoxy)methyl]benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | p-nitrophenol sodium salt | HCID 13214 | — |
| Reactant | 4-Methyloxybenzyl chloride | HCID 69993 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 1-Methoxy-4-[(4-nitrophenoxy)methyl]benzene | HCID 298745 | — |
Reaction Steps
To a solution of 24.2 g of sodium p-nitrophenoxide in 60 ml of DMF was added 23.5 g of 4-methoxybenzyl chloride. The precipitate was collected after 24 hours, washed with water, and recrystallized from chloroformcyclohexane, providing 1-methoxy-4-[(4-nitrophenoxy)methyl]benzene, mp 122°-124° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04588730 |
| Source dataset | uspto-grants-1986_05 |
| ORD ID | ord-82884560de3541c2b2659bb490b293c7 |
| Source note | uspto-grants-1986_05 |