Ethylene → Cyclohexane, [(trichlorosilyl)methyl]-

HRID 280362Notes

Reaction equation

HRID 280362 reaction equation
[Cl:1][SiH:2]([Cl:4])[Cl:3].[CH3:5][C:6]1[CH2:11][CH2:10][CH2:9][CH2:8][CH:7]=1.C=C>C(Cl)(Cl)Cl>[Cl:1][Si:2]([CH2:5][CH:6]1[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7]1)([Cl:4])[Cl:3]

Participants

5

Reactant 3

HCID 6325EthyleneHCID 115741-MethylcyclohexeneHCID 24811Trichlorosilane

Product 1

HCID 87618Cyclohexane, [(trichlorosilyl)methyl]-

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

A mixture of 20 ml trichlorosilane, 25 ml chloroform, 8.1 g 1-methylcyclohexene and 0.055 g (phenazine)PtCl2 (C2H4) was refluxed and stirred under nitrogen for 6 days. Distillation of the reaction mixture afforded 2.2 g of trichlorosilylmethylcyclohexane C6H11CH2SiCl3 which was characterized by its mass and NMR spectra.

Workup

  1. temperaturewas refluxed
  2. distillationDistillation of the reaction mixture

Sources & evidence

ORD record
ord-abc6d32437f54e5ab25df4dc23bd3d26
Source dataset
uspto-grants-1986_05
Patent number
US04588800

Reaction notes

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