Methanol → HCID 564562, compound

HRID 280406Notes

Reaction equation

HRID 280406 reaction equation
[C:1]([NH:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)(=[O:6])[CH2:2][CH:3]=[CH:4][CH3:5].CO>N1C=CC=CC=1>[C:1]([NH:7][C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1)(=[O:6])[CH:2]=[CH:3][CH2:4][CH3:5]

Participants

4

Reactant 2

HCID 887MethanolHCID 564800HCID 564800, compound

Product 1

HCID 564562HCID 564562, compound

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

52.6 g of pent-3-enanilide, 19.2 g of methanol, 4.75 g of pyridine and 2.05 g of Co2 (CO)8 were reacted analogously to Example 1 for 1.5 hours at 170° C. At a pentenanilide conversion of 58.3 mol %, C6 -dicarboxylic acid methylesteranilides were formed at a selectivity S of conversion of 37.5 mol % (11 =65.3%).

Sources & evidence

ORD record
ord-ce1be37f37e44fe6914eda0ef3c8a7f6
Source dataset
uspto-grants-1986_05
Patent number
US04588833

Reaction notes

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