Hydrogen Bromide → HCID 12717836, compound

HRID 28082Notes

Reaction equation

HRID 28082 reaction equation
[N:1]12C[N:5]3[CH2:6][P:7]([CH2:9][N:3](C3)C1)[CH2:8]2.[BrH:11]>O>[BrH:11].[BrH:11].[BrH:11].[NH2:5][CH2:6][P:7]([CH2:9][NH2:3])[CH2:8][NH2:1]

Participants

4

Reactant 2

HCID 260Hydrogen BromideHCID 1430611,3,5-Triaza-7-phosphaadamantane

Product 1

HCID 12717836HCID 12717836, compoundYield 74.2%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Following the procedure outline in Example 6, 3.14 g (0.02 mol) of 1,3,5-triaza-7-phosphaadamantane was hydrolyzed with a solution of 25 g (0.15 mol) of 48% hydrobromic acid and 40 g of water, giving, after workup, 5.4 g (74% yield) of tris(aminomethyl)phosphine trihydrobromide as a white, crystalline solid, dec. 214° C. without melting.

Workup

  1. customgiving

Sources & evidence

ORD record
ord-6f35931efedf45a5b13861590a114ab2
Source dataset
uspto-grants-1980_09
Patent number
US04225512

Reaction notes

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