Trimethyl phosphite → Phosphinecarboxylic acid, dimethoxy-, butyl ester, oxide

HRID 280865Notes

Reaction equation

HRID 280865 reaction equation

C[O:2][P:3]([O:6][CH3:7])[O:4][CH3:5].Cl[C:9]([O:11][CH2:12][CH2:13][CH2:14][CH3:15])=[O:10]>>[CH2:12]([O:11][C:9]([P:3](=[O:2])([O:6][CH3:7])[O:4][CH3:5])=[O:10])[CH2:13][CH2:14][CH3:15]

Participants

3

Reactant 2

HCID 8472Trimethyl phosphite

HCID 61140Butyl chloroformate

Product 1

HCID 512108Phosphinecarboxylic acid, dimethoxy-, butyl ester, oxide

Procedure

From 10.0 ml (85 mmole) of trimethylphosphite and 8.7 g (64 mmole) of n-butyl chloroformate. (100° C., 1.5 hours).

Workup

custom(100° C., 1.5 hours)

Sources & evidence

ORD record: ord-8e238985d366458d98f4814853e9c626
Source dataset: uspto-grants-1986_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04591583

Reaction notes

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