Acetate → HCID 57831043, compound

HRID 287332Notes

Reaction equation

HRID 287332 reaction equation
[Br:1][c:2]1[n:3][c:4]2[c:5]([n:6][cH:7]1)[n:8]([CH2:17][O:18][CH2:19][CH2:20][Si:21]([CH3:22])([CH3:23])[CH3:24])[cH:9][c:10]2[C:11]([C:12]([CH3:13])([CH3:14])[CH3:15])=[O:16].[C:101]([O-:102])(=[O:103])[CH3:104].[C:25]([c:26]1[cH:27][cH:28][cH:29][cH:30][cH:31]1)([c:32]1[cH:33][cH:34][cH:35][cH:36][cH:37]1)=[NH:38].[C:39](=[O:40])([O-:41])[O-:42].[C:96]([O-:97])(=[O:98])[CH3:99].[Cs+:43].[Cs+:44].[O:91]1[CH2:92][CH2:93][CH2:94][CH2:95]1.[Pd+2:100].[cH:45]1[cH:46][cH:47][c:48]([P:49]([c:50]2[cH:51][cH:52][c:53]3[c:54]([cH:55][cH:56][cH:57][cH:58]3)[c:59]2-[c:60]2[c:61]3[c:62]([cH:63][cH:64][cH:65][cH:66]3)[cH:67][cH:68][c:69]2[P:70]([c:71]2[cH:72][cH:73][cH:74][cH:75][cH:76]2)[c:77]2[cH:78][cH:79][cH:80][cH:81][cH:82]2)[c:83]2[cH:84][cH:85][cH:86][cH:87][cH:88]2)[cH:89][cH:90]1>>[c:2]1([N:38]=[C:25]([c:26]2[cH:27][cH:28][cH:29][cH:30][cH:31]2)[c:32]2[cH:33][cH:34][cH:35][cH:36][cH:37]2)[n:3][c:4]2[c:5]([n:6][cH:7]1)[n:8]([CH2:17][O:18][CH2:19][CH2:20][Si:21]([CH3:22])([CH3:23])[CH3:24])[cH:9][c:10]2[C:11]([C:12]([CH3:13])([CH3:14])[CH3:15])=[O:16]

Participants

9

Reactant 8

HCID 175Acetate2×HCID 8028TetrahydrofuranHCID 19660Carbonate IonHCID 104967Cesium cation2×HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 136809Benzophenone imineHCID 634876Binap, (A+-)-HCID 578292211-(2-bromo-5-((2-(trimethylsilyl)ethoxy)methyl)-5H-pyrrolo[2,3-b]pyrazine-7-yl)-2,2-dimethylpropane-1-one

Product 1

HCID 57831043HCID 57831043, compound

Sources & evidence

ORD record
ord-bd44fa3e10a842049c0ac696066ffe62
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

Loading…