Acetate → 1-(1H-inden-2-yl)-2-methylindole

HRID 288518Notes

Reaction equation

HRID 288518 reaction equation
[Br:25][C:26]1=[CH:30][c:29]2[c:28]([cH:34][cH:33][cH:32][cH:31]2)[CH2:27]1.[CH2:1]1[C:2]([n:10]2[cH:11][cH:12][cH:13][cH:14]2)=[CH:3][c:4]2[cH:5][cH:6][cH:7][cH:8][c:9]21.[CH3:15][c:16]1[nH:17][c:18]2[cH:19][cH:20][cH:21][cH:22][c:23]2[cH:24]1.[CH3:52][O:53][CH2:54][CH2:55][O:56][CH3:57].[CH3:58][c:59]1[cH:60][cH:61][cH:62][cH:63][cH:64]1.[K+:40].[K+:41].[K+:42].[O-:44][C:45]([CH3:46])=[O:47].[O-:48][C:49]([CH3:50])=[O:51].[P:35]([O-:36])([O-:37])([O-:38])=[O:39].[Pd+2:43]>>[CH2:1]1[C:2]([n:17]2[c:16]([CH3:15])[cH:24][c:23]3[c:18]2[cH:19][cH:20][cH:21][cH:22]3)=[CH:3][c:4]2[cH:5][cH:6][cH:7][cH:8][c:9]21

Participants

10

Reactant 9

HCID 175Acetate2×HCID 813Potassium Cation3×HCID 1061PhosphateHCID 1140TolueneHCID 72242-MethylindoleHCID 80711,2-DimethoxyethaneHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 5755861H-Indene, 2-bromo-HCID 180083501-(1H-inden-2-yl)-1H-pyrrole

Product 1

HCID 695023241-(1H-inden-2-yl)-2-methylindole

Sources & evidence

ORD record
ord-f8721ea01c154f91ab8b11c344d4f1ec
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

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