HRID290134

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID813

Potassium cation

K+

2 次

HCID923

Sodium ion

Na+

HCID19660

Carbonate

CO3-2

HCID33558

Azide

N3-

HCID85570

Tosylate

C7H7O3S-

HCID2733958

2-Methoxyphenylboronic acid

C7H9BO3

结构：Cc1ccc(S(=O)(=O)OCC2Cc3cccc(Br)c3O2)cc1

HCID58747572

未命名化合物

结构：COc1ccccc1-c1cccc2c1OC(COS(=O)(=O)c1ccc(C)cc1)C2

HCID86599090

未命名化合物

PRODUCTS

生成物

结构：COc1ccccc1-c1cccc2c1OC(CN=[N+]=[N-])C2

HCID86599203

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-1119811baf2c45238ad2835c674d576f
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (8/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (8/10)

反应 SMILES

[C:34](=[O:35])([O-:36])[O-:37].[CH3:1][c:2]1[cH:3][cH:4][c:5]([S:6]([O:7][CH2:8][CH:9]2[CH2:10][c:11]3[cH:12][cH:13][cH:14][c:15]([Br:16])[c:17]3[O:18]2)(=[O:19])=[O:20])[cH:21][cH:22]1.[CH3:23][O:24][c:25]1[cH:26][cH:27][cH:28][cH:29][c:30]1[B:31]([OH:32])[OH:33].[CH3:40][c:41]1[cH:42][cH:43][c:44]([S:45]([O:46][CH2:51][CH:52]2[O:53][c:54]3[c:55]([cH:57][cH:58][cH:59][c:60]3-[c:61]3[c:62]([O:67][CH3:68])[cH:63][cH:64][cH:65][cH:66]3)[CH2:56]2)(=[O:47])=[O:48])[cH:49][cH:50]1.[K+:38].[K+:39].[N-:81]=[N+:82]=[N-:83].[Na+:80].[O-:69][S:70]([c:71]1[cH:72][cH:73][c:74]([CH3:75])[cH:76][cH:77]1)(=[O:78])=[O:79]>>[CH2:51]([CH:52]1[O:53][c:54]2[c:55]([cH:57][cH:58][cH:59][c:60]2-[c:61]2[c:62]([O:67][CH3:68])[cH:63][cH:64][cH:65][cH:66]2)[CH2:56]1)[N:81]=[N+:82]=[N-:83]