Potassium Cation → 6-Benzyloxy-2,2-dimethyl-3,4-epoxychroman

HRID 292668Notes

Reaction equation

HRID 292668 reaction equation
[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][c:9]1[cH:10][c:11]2[c:16]([cH:17][cH:18]1)[O:15][C:14]([CH3:19])([CH3:20])[CH:13]([Br:21])[CH:12]2[OH:22].[CH2:25]1[O:26][CH2:27][CH2:28][CH2:29]1.[K+:24].[OH-:23]>>[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][c:9]1[cH:10][c:11]2[c:16]([cH:17][cH:18]1)[O:15][C:14]([CH3:19])([CH3:20])[CH:13]1[CH:12]2[O:22]1

Participants

5

Reactant 4

HCID 813Potassium CationHCID 961HydroxideHCID 8028TetrahydrofuranHCID 195933326-Benzyloxy-3-bromo-2,2-dimethyl-chroman-4-ol

Product 1

HCID 109240076-Benzyloxy-2,2-dimethyl-3,4-epoxychroman

Sources & evidence

ORD record
ord-5f389707720746e39c716215b4dd6364
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

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