Bicarbonate Ion → 5-Fluoro-2-tri-n-butylstannylfuran

HRID 296031Notes

Reaction equation

HRID 296031 reaction equation
[Br:15][c:16]1[cH:17][cH:18][c:19]([F:21])[o:20]1.[Br:1][c:2]1[o:3][c:4]([C:5]([OH:6])=[O:7])[cH:8][cH:9]1.[C:10](=[O:11])([OH:12])[O-:13].[CH2:22]([Li:23])[CH2:24][CH2:25][CH3:26].[CH2:27]([CH2:28][CH2:29][CH3:30])[Sn:31]([CH2:32][CH2:33][CH2:34][CH3:35])([CH2:36][CH2:37][CH2:38][CH3:39])[Cl:40].[CH3:42][CH2:43][CH2:44][CH2:45][CH3:46].[CH3:47][CH2:48][CH2:49][CH2:50][CH3:51].[Na+:14].[OH2:41]>>[c:16]1([Sn:31]([CH2:27][CH2:28][CH2:29][CH3:30])([CH2:32][CH2:33][CH2:34][CH3:35])[CH2:36][CH2:37][CH2:38][CH3:39])[cH:17][cH:18][c:19]([F:21])[o:20]1

Participants

9

Reactant 8

HCID 769Bicarbonate IonHCID 923Sodium ionHCID 962WaterHCID 8003Pentane2×HCID 15096Tributyltin ChlorideHCID 685115-Bromo-2-furanecarboxylic acidHCID 220520202-Bromo-5-fluorofuranHCID 178418339Butyllithium

Product 1

HCID 686164745-Fluoro-2-tri-n-butylstannylfuran

Sources & evidence

ORD record
ord-11950526b076448faba3826b7d0e7fce
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

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