Acetate → 2-butyl-6-methoxy-2-(2-oxopropyl)-3,4-dihydro-1(2H)-naphthalenone

HRID 301977Notes

Reaction equation

HRID 301977 reaction equation
[C:21]1(=[O:22])[CH:23]=[CH:24][C:25](=[O:27])[CH:26]=[CH:28]1.[CH2:1]([CH:2]=[CH2:3])[C:4]1([CH2:17][CH2:18][CH2:19][CH3:20])[C:5](=[O:16])[c:6]2[cH:7][cH:8][c:9]([O:14][CH3:15])[cH:10][c:11]2[CH2:12][CH2:13]1.[CH3:35][C:36]#[N:37].[Cl+3:30]([OH:31])([O-:32])([O-:33])[O-:34].[O-:39][C:40]([CH3:41])=[O:42].[O-:43][C:44]([CH3:45])=[O:46].[OH2:29].[Pd+2:38]>>[CH2:1]([C:2]([CH3:3])=[O:27])[C:4]1([CH2:17][CH2:18][CH2:19][CH3:20])[C:5](=[O:16])[c:6]2[cH:7][cH:8][c:9]([O:14][CH3:15])[cH:10][c:11]2[CH2:12][CH2:13]1

Participants

8

Reactant 7

HCID 175Acetate2×HCID 962WaterHCID 4650QuinoneHCID 6342AcetonitrileHCID 24247Perchloric AcidHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 586040462-allyl-2-butyl-6-methoxy-3,4-dihydro-1(2H)-naphthalenone

Product 1

HCID 586040662-butyl-6-methoxy-2-(2-oxopropyl)-3,4-dihydro-1(2H)-naphthalenone

Sources & evidence

ORD record
ord-3233add583af4a97b4b94977088af8b2
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

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