Acetate → 4'-Ethoxybiphenyl-4-carbaldehyde

HRID 310534Notes

Reaction equation

HRID 310534 reaction equation
[Br:36][c:37]1[cH:38][cH:39][c:40]([CH:41]=[O:42])[cH:43][cH:44]1.[C:1]([P:2]([C:3]([CH3:4])([CH3:5])[CH3:6])[c:7]1[cH:8][cH:9][cH:10][cH:11][c:12]1-[c:13]1[cH:14][cH:15][cH:16][cH:17][cH:18]1)([CH3:19])([CH3:20])[CH3:21].[C:45]([O-:46])(=[O:47])[CH3:48].[C:50]([O-:51])(=[O:52])[CH3:53].[CH2:22]([CH3:23])[O:24][c:25]1[cH:26][cH:27][c:28]([B:31]([OH:32])[OH:33])[cH:29][cH:30]1.[F-:34].[K+:35].[Pd+2:49]>>[CH2:22]([CH3:23])[O:24][c:25]1[cH:26][cH:27][c:28](-[c:37]2[cH:38][cH:39][c:40]([CH:41]=[O:42])[cH:43][cH:44]2)[cH:29][cH:30]1

Participants

8

Reactant 7

HCID 175Acetate2×HCID 813Potassium CationHCID 28179Fluoride IonHCID 707414-BromobenzaldehydeHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 27342152-(Di-tert-butylphosphino)biphenylHCID 27343514-Ethoxyphenylboronic acid

Product 1

HCID 13927554'-Ethoxybiphenyl-4-carbaldehyde

Sources & evidence

ORD record
ord-3bba7bb47435406990a6447c83a4d760
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

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