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HRID31698

反应详情

EQUATION

反应方程式

HRID 31698 的结构方程式

REACTANTS

反应物

3
结构：O=C(OO)c1cccc(Cl)c1
HCID70297

Benzenecarboperoxoic acid, 3-chloro-

C7H5ClO3

结构：CC1(CCO)OCC2(CO1)OCCCO2
HCID59792508

未命名化合物

结构：Cc1c(OCC2(C)OCC3(CO2)OCCO3)ccnc1CS(=O)c1nc2ccccc2[nH]1.[Na]
HCID66776550

未命名化合物

PRODUCTS

生成物

1
结构：CC1(CCOc2ccnc(CS(=O)c3nc4ccccc4[nH]3)c2)OCC2(CO1)OCCCO2.[Na]
HCID66776265

未命名化合物

收率 11.4%

PROCEDURE

实验过程

The same procedure as in the steps (5d) to (5h) of Example 5 (a reprecipitation operation was not performed in oxidation step with 3-chloroperbenzoic acid) was repeated using 2-(9-methyl-1,5,8,10-tetraoxaspiro[5.5]undec-9-yl)ethanol obtained in the step (76d) above to obtain the title compound (228 mg, total 11.4% yield) as a white solid.

WORKUP

后处理

  1. customobtained in the step (76d) above